Chemistry - A European Journal · 2009 · 195 citations · 27 references
Natural SciencesChemistryMaterials ScienceMaterials ChemistryOptical MaterialsOrganic ChemistryOrganic Electronic MaterialsOrganic SemiconductorsPhotochemical SynthesisPhotochemistrySolar Cell MaterialsSolar CellsBoron ChemistryChromophore DesignDye-sensitized Solar CellsStructure-property Relationships In Dyes
Fun in the sun! A strategy has been devised for functionalizing and solubilizing boron dipyrromethene (Bodipy) dyes at the central boron atom and changing the color by increasing delocalization on the central core. This approach leads to the formation of stable B-C[triple bond]C and pyrrole--C=C linkages suitable for use in TiO(2)-sensitized devices (see figure).
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Mohammad Khaja Nazeeruddin, Andreas Kay, I. Rodicio et al. · Journal of the American Chemical Society · 1993 · 6K citations · Full text