Angewandte Chemie International Edition in English · 1972 · 94 citations · 60 references
Natural SciencesChemistryOrganic ChemistryOrganometallic ChemistrySupramolecular ChemistryElimination ReactionsOrganic SynthesisReaction MechanismsAnti EliminationBimolecular ReactionsStereochemistry Of EliminationSteric Effects On Elimination
Abstract Earlier evidence led to the view that in bimolecular olefin‐forming eliminations the anti steric course is generally preferred over the syn. Recent experiments, however, show that in some common bimolecular elimination reactions, notably those involving onium bases, syn‐ and anti‐eliminations proceed side by side, the former preferentially leading to the trans‐ and the latter to the cis‐olefins.
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Structure and Mechanism in Organic Chemistry
G. de Jong · Chemical Engineering Science · 1954 · 735 citations
Juergen Schwarz · Carbohydrate Research · 1966 · 173 citations
Chemical effects of steric strains—XIV
Herbert C. Brown, K. ICHIKAWA · Tetrahedron · 1957 · 127 citations