Applied Organometallic Chemistry · 2009 · 14 citations · 33 references
Natural SciencesChemical EngineeringChemistryCatalysisPolymer ChemistryReaction EngineeringCatalyst DesignCatalyst PreparationCatalyst SynthesisCatalytic MaterialsCatalytic Reaction EngineeringSupported CatalystsHeck ReactionHeterogeneous Catalyst DesignHeterogeneous Catalyst PreparationHeterogeneous Catalyst SynthesisMesoporous MaterialsPalladium CatalystsPalladium-catalyzed Cross-couplingSilica Surface Functionalization
Abstract A new catalytic system based on Pd supported on polyether‐functionalized mesoporous silica was prepared. This material was obtained by co‐hydrolysis and polycondensation of tetraethylorthosilicate and a bis‐silylated triblock copolymer P123 ( M w = 5800) followed by the decomposition of Pd(OAc) 2 salt. We have shown that this material can be applied as powerful heterogeneous catalyst for the Heck coupling reaction. Copyright © 2009 John Wiley & Sons, Ltd.
33
Dongyuan Zhao, Qisheng Huo, Jianglin Feng et al. · Journal of the American Chemical Society · 1998 · 6.6K citations