Concepedia

The palladium(II) coordination chemistry of ferrocenylphosphinobipyridines: a novel trans-chelating ligand system

Ian R. Butler, M. Kalaji, Louise Nehrlich, M Hursthouse, Alexander Karaulov, K. M. Abdul Malik

Journal of the Chemical Society Chemical Communications · 1995 · 36 citations · 8 references

DOI

Concepts

Abstract

The reaction of dichloro(cycloocta-1,5-diene)palladium(II) with l-dipheny (L1) or 1-phenyl(n-butyl)-phosphino-1′-[6-(2,2′-bipyridyl)]ferrocene (L2) results in the novel trans-coordination geometry with the β-pyridinyl ring and the phosphine group binding to the metal centre, as proved by a crystal structure determination of [PdCl2L1][PdCl2(cod)].

References

8

Phase annealing in SHELX-90: direct methods for larger structures

George M. Sheldrick · Acta Crystallographica Section A Foundations of Crystallography · 1990 · 16.3K citations

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Asymmetric Synthesis Catalyzed by Chiral Ferrocenylphosphine–Transition Metal Complexes. I. Preparation of Chiral Ferrocenylphosphines

Tamio Hayashi, Takaya Mise, Motoo Fukushima et al. · Bulletin of the Chemical Society of Japan · 1980 · 452 citations

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A dimeric calcium siloxide lightly stabilized by ammonia ligands

Jawwad A. Darr, Simon R. Drake, Michael B. Hursthouse et al. · Inorganic Chemistry · 1993 · 231 citations

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Bipyridyl-metal complexes. 2. Synthesis and characterization of palladium(II) chloride complexes of 6-ferrocenyl-2,2'-bipyridine, 2-ferrocenyl-1,10-phenanthroline, and 6-ruthenocenyl-2,2'-bipyridine, and the single-crystal x-ray structure of (1,1'-bis(2,2'-bipyrid-6-yl)ferrocene-N,N')palladium chloride

Ian R. Butler · Organometallics · 1992 · 92 citations

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Asymmetric hydrogenation catalyzed by cationic ferrocenylphosphine rhodium(I) complexes and the crystal structure of a catalyst precursor

Frederick W. B. Einstein, Anthony C. Willis, E. Shan Yeh · Journal of the American Chemical Society · 1980 · 77 citations

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