Chemical Communications · 2011 · 57 citations · 21 references
Natural SciencesBiochemistryBiophysicsBiophysical ChemistryMolecular OncologyFluorescence SpectroscopyNon-photochemical QuenchingPhotochemical KineticsPhotochemistryPhotodynamic TherapyReactive Oxygen SpeciesCancer Photodynamic TherapyPh DependencePhotophysical MechanismsPhotosensitizersSinglet Oxygen ChemistrySinglet Oxygen FormationSinglet Oxygen GenerationSinglet Oxygen Quenching
5,10,15,20-Tetrakis(N-(2-(1H-imidazol-4-yl)ethyl)benzamide)porphyrin produced twice as many singlet oxygen ((1)O(2)) molecules at pH 5.0 (quantum yield 0.53 ± 0.01) than at pH 7.4, whereas the (1)O(2) quenching rate was reduced by a factor of 2.5 for a pH change from 7.4 to 5.0.
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