Gold‐ or Platinum‐Catalyzed Tandem Cycloisomerization/Prins‐Type Cyclization Reactions

Abstract

Straightforward and efficient: Functionalized eight-membered carbocycles are easily obtained from simple allyl-substituted 5-hexyn-1-ol derivatives by a catalytic tandem sequence involving a 6-exo cycloisomerization followed by a Prins-type cyclization (see scheme). Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z503874_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.