Concepedia

Activation of CCl and CH Bonds by Ligated S<sub>2</sub><sup>2−</sup> Ions: Conversion of Organic Chlorides into Organosulfur Compounds in <i>cis‐</i>[(IrCp*)<sub>2</sub>(μ‐CH<sub>2</sub>)<sub>2</sub>(μ‐S<sub>2</sub>R)]<sup>+</sup>

Tarlok S. Lobana, Kiyoshi Isobe, Hiroaki Kitayama, Takanori Nishioka, Isamu Kinoshita

Angewandte Chemie International Edition · 2003 · 13 citations · 22 references

DOI

Concepts

Abstract

Cleaning up with sulfur: The multiple CCl bonds of toxic, polychlorinated organic compounds can be activated by the coordinated S2 ligand of complex 1. For example, reaction of 1 with C6H5-CHCl2 or C6H5-CCl3 in methanol forms a dithiobenzoate complex, which on addition of NaBPh4 provides complex 2; Cp*=C5Me5.

References

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Oxidative Addition of Carbon−Chloride Bonds to Rhodium(I) Complexes Containing Terdentate Nitrogen Ligands. X-ray Analyses of Rhodium(I) Chloride and Rhodium(III) Chloromethyl Complexes

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Cooperative Bimetallic Effects on New Iridium(III) Pyrazolate Complexes:  Hydrogen−Hydrogen, Carbon−Hydrogen, and Carbon−Chlorine Bond Activations

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Oxidative-addition reactions of alkyl chlorides with chlorobis(cyclooctene)rhodium(I) and the bis(oxazolinyl)pyridine ligand: formation of stable (chloromethyl)rhodium(III) complexes and their reactions

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Copper-catalyzed facile carbon-carbon bond forming reactions at the α-position of α,α,γ-trichlorinated γ-lactams

Sho-ichi Iwamatsu, Hideo Kondo, Kouki Matsubara et al. · Tetrahedron · 1999 · 51 citations

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