Physicochemical investigation of <i>k</i>‐carrageenan in the random state

Abstract

Abstract Light‐scattering, viscosity, and sedimentation experiments on aqueous solutions of k ‐carrageenan show that this sulfated polygalactose is an expanded flexible random coil. This expansion is due to long‐range interactions that are predominantly electrostatic. Extrapolation of viscosity data to infinite ionic strength provided values for the intrinsic viscosity which were subjected to the Stockmayer‐Fixman analysis, giving a value for the Mark‐Houwink coefficient under theta‐conditions, K θ , of 0.27. The characteristic ratio, C ∞ , under these conditions is 7.8, and the conformation factor σ is 2. In a solution of 0.118 ionic strength, where a Mark‐Houwink exponent a η of 0.86 is found, the radii of gyration calculated from viscosity data are lower than those found from the angular dependence of scattered light. On the other hand, the radius of gyration found from the sedimentation rate agrees well with the light‐scattering radius. The relations between molecular parameters are corrected for the poly‐dispersity of the sample.