Concepedia

Iron-catalyzed olefin hydrogenation at 1 bar H<sub>2</sub> with a FeCl<sub>3</sub>–LiAlH<sub>4</sub> catalyst

Tim N. Gieshoff, Matteo Villa, Alice Welther, Markus Plois, Uttam Chakraborty, Robert Wolf, Axel Jacobi von Wangelin

Green Chemistry · 2015 · 66 citations · 48 references

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Concepts

Abstract

The scope and mechanism of a practical protocol for the iron-catalyzed hydrogenation of alkenes and alkynes at 1 bar H<sub>2</sub> pressure were studied.

References

48

Preparation and Molecular and Electronic Structures of Iron(0) Dinitrogen and Silane Complexes and Their Application to Catalytic Hydrogenation and Hydrosilation

Suzanne C. Bart, Emil B. Lobkovsky, Paul J. Chirik · Journal of the American Chemical Society · 2004 · 818 citations

, , +16

Free-radical clocks

D. Griller, K. U. Ingold · Accounts of Chemical Research · 1980 · 808 citations

, , +5

Competition Methods and Scales for Alkyl Radical Reaction Kinetics

Martin Newcomb · Tetrahedron · 1993 · 617 citations

, , +12

Preparation, Structure, and Reactivity of Nonstabilized Organoiron Compounds. Implications for Iron-Catalyzed Cross Coupling Reactions

Alois Fürstner, Rubén Martı́n, Helga Krause et al. · Journal of the American Chemical Society · 2008 · 474 citations

, , +15

Homogeneous catalysis using iron complexes: recent developments in selective reductions

Kathrin Junge, Kristin Schröder, Matthias Beller · Chemical Communications · 2011 · 453 citations

, , +17