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Preparation and X-ray crystal and molecular structure of di-µ-diphenylphosphido-bis(triphenylphosphinecarbonyliridium)
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1973
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X-ray CrystallographyInorganic ChemistryX-ray CrystalDifferent Iridium HydridesMetal AtomsEngineeringCrystal StructureNatural SciencesOrganic ChemistryMain Group ChemistryChemistryTitle CompoundCrystallographyCrystal Structure DesignInorganic Compound
In the title compound, obtained from two different iridium hydrides in boiling DMF, the two metal atoms are connected by a formal double bond 2·551(1)Å; long, and are bridged by two diphenylphosphido-ligands.