Polymer · 2008 · 3.3K citations · 259 references
Natural SciencesMaterials EngineeringMaterials ScienceNanomaterialsNanotechnologyPolymer MaterialsComposite MaterialsNanocompositesPolymer CompositesPolymer NanocompositesPolymer-matrix CompositesPolymeric NanomaterialsBiomedical ApplicationsClay NanocompositesGlass TransitionGlass Transition BehaviorNanocomposite MaterialsPolymer Barrier PropertiesPolymer Glass TransitionPolymeric Nanocomposites
Polymer matrix nanocomposites, especially exfoliated clay-based ones, dominate current nanotechnology research, with studies addressing the nano‑effect on crystallization, glass transition, and a range of properties such as barrier, flammability, biomedical, electrical/optoelectronic, and fuel cell performance. The review aims to detail the technology of exfoliated clay-based nanocomposites and cover other key areas such as barrier, flammability, biomedical, electrical/optoelectronic, and fuel cell applications. The review surveys the technology of exfoliated clay-based nanocomposites and examines their barrier, flammability, biomedical, electrical/optoelectronic, and fuel cell applications.
In the large field of nanotechnology, polymer matrix based nanocomposites have become a prominent area of current research and development. Exfoliated clay-based nanocomposites have dominated the polymer literature but there are a large number of other significant areas of current and emerging interest. This review will detail the technology involved with exfoliated clay-based nanocomposites and also include other important areas including barrier properties, flammability resistance, biomedical applications, electrical/electronic/optoelectronic applications and fuel cell interests. The important question of the "nano-effect" of nanoparticle or fiber inclusion relative to their larger scale counterparts is addressed relative to crystallization and glass transition behavior. Of course, other polymer (and composite)-based properties derive benefits from nanoscale filler or fiber addition and these are addressed.
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