Publication | Closed Access
Novel V<sup>III</sup> Complexes with a Central [V<sub>3</sub>(μ<sub>3</sub>‐S)‐(μ‐S<sub>2</sub>)<sub>3</sub>]<sup>+</sup> or [V<sub>2</sub>(μ‐O)(μ‐SPh)<sub>2</sub>]<sup>2+</sup> Unit
26
Citations
28
References
1993
Year
Inorganic ChemistryEngineeringPhysicsNatural SciencesVanadium ComplexesCoordination ComplexPhysical ChemistryMolecular ComplexChemistryS LigandsV3 TriangleInorganic SynthesisBiophysicsInorganic Compound
Positioned in the middle of the V3 triangle in complex 1, whose edges are bridged asymmetrically by three S ligands, is a μ3-sulfido ligand (the central unit of 1 is shown on the right). In addition each V atom is coordinated to a terminal bipyridyl ligand. This structure type is new for vanadium complexes.
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