Angewandte Chemie International Edition · 2010 · 309 citations · 28 references
Natural SciencesChemical EngineeringChemistryMaterials ChemistryPolymer ChemistrySolid-state ChemistryAdsorption At InterfacesCoordination ChemistryCoordination PolymersInorganic MaterialsPorous MaterialsSolid-gas InterfacesAdsorption PropertiesAdsorption SeparationMetal-organic FrameworksPorous Adsorbent MaterialsPorous AdsorbentsPorous Coordination PolymersPorous PolymersTwo-dimensional Coordination Polymers
My flexible friend: Separation of a CO2/CH4 mixture was optimized by varying the composition of solid solutions of interdigitated 2D frameworks comprising two different isophthalate ligands (see picture). The characteristics of the solid solutions were dependent on the ligand ratio, which influenced the inherent flexibility and therefore the adsorption properties of the frameworks.
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A route to high surface area, porosity and inclusion of large molecules in crystals
Hee K. Chae, Diana Y. Siberio-Pérez, Jaheon Kim et al. · Nature · 2004 · 2.8K citations · Full text
Multiple Functional Groups of Varying Ratios in Metal-Organic Frameworks
Hexiang Deng, Christian J. Doonan, Hiroyasu Furukawa et al. · Science · 2010 · 1.9K citations