Direct Palladium‐Catalyzed Intermolecular Allylation of Highly Electron‐Deficient Polyfluoroarenes

Abstract

A simple operation: The use of readily available PPh3, high reaction efficiency, and good stereo- and regioselectivity provided useful and operationally simple access to polyfluoroarylated derivatives through the title transformation (see scheme; phen=1,10-phenanthroline). The reaction mechanism was also studied. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.