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A Trigonal‐Bipyramidal Cyanide Cluster with Single‐Molecule‐Magnet Behavior: Synthesis, Structure, and Magnetic Properties of {[Mn<sup>II</sup>(tmphen)<sub>2</sub>]<sub>3</sub>[Mn<sup>III</sup>(CN)<sub>6</sub>]<sub>2</sub>}
276
Citations
24
References
2003
Year
Relaxation ProcessMagnetic PropertiesEngineeringLow-dimensional MagnetismSlow Paramagnetic RelaxationMagnetic ResonanceOne-dimensional MagnetismAc Susceptibility MeasurementsChemistryMagnetic MaterialsMagnetismNuclear Quadrupole ResonanceRelaxometryMolecular MagnetismInorganic ChemistryMaterials SciencePhysicsTrigonal‐bipyramidal Cyanide ClusterLow-dimensional SystemsMagnetoelasticityMagnetic MaterialCrystallographyQuantum MagnetismLow TemperaturesMolecule-based MagnetNatural SciencesCondensed Matter PhysicsApplied PhysicsDynamic Nuclear PolarizationCluster ChemistrySingle‐molecule‐magnet BehaviorMolecule-based MaterialFunctional Materials
Slow paramagnetic relaxation was observed at low temperatures from ac susceptibility measurements in the form of a frequency-dependent out-of-phase (χ) signal for the title complex (see picture). This provides compelling evidence that this cluster is a rare example of a cyanide-bridged single-molecule magnet. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2003/z50479_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.
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