Concepedia

Lithium‐Tellurium Exchange: A New Entry to Organolithium Compounds

Tomoki Hiiro, Nobuaki Kambe, Akiya Ogawa, Noritaka Miyoshi, Shinji Murai, Noboru Sonoda

Angewandte Chemie International Edition in English · 1987 · 117 citations · 19 references

DOI

Concepts

Abstract

Compounds of the type Rli , with R PhC°C, PhCH 2 Ph, CH 2  CHCH 2 , alkyl, Me 3 SiCH 2 , PhCH 2 OCH 2 , etc., can be generated in an indirect way by the route shown below. In a one‐pot procedure, the tellurides are formed directly from alkyl halides and tellurolates RTeLi. The procedure particularly valuable when conventional lithium‐halogen exchange is not possible. equation image

References

19

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