Rational Design of Sugar‐Based‐Surfactant Combined Catalysts for Promoting Glycerol as a Solvent

Ayman Karam, Nicolas Villandier, Mathieu Delample, Carmen Klein Koerkamp, Jean‐Paul Douliez, Robert Granet, Pierre Krausz, Joël Barrault, François Jérôme

Chemistry - A European Journal · 2008 · 52 citations · 21 references

Abstract

A sugary treat: Here we report the great efficiency of sugar-based-surfactant combined catalysts for conducting selective base-catalyzed organic reactions in glycerol. Close control of the reaction selectivity was successfully obtained owing to the formation of catalytic hydrophobic pockets in glycerol (see figure). The advantages of our catalytic processes and its similarities with catalysis in water are also highlighted. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.

References

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