Synthesis and X-ray crystal structure of a 1,1-dithiolate cluster anion containing an Ag<sub>6</sub><sup>1</sup>octahedron [Ag<sub>6</sub><sup>1</sup>{s<sub>2</sub>cc(cn)<sub>2</sub>}<sub>6</sub>]<sup>6–</sup>

Hans Dietrich, W. Storck, Georg Manecke

Journal of the Chemical Society Chemical Communications · 1982 · 27 citations · 0 references

Concepts

Abstract

The existence of the novel title anion, despite its high electrical charge and the surprising fact that its ag6S12core has the same size as that in the uncharged molecule [Ag61{S2C-N(C3H7)2}6],1 must be due to Ag–Ag interactions.