Concepedia

Replacement of hydrido-ligands in [Ru3(µ-H)3(µ-H)3(µ3-COMe)(CO)9] and [Ru4(µ-H)4(CO)12] by triphenylphosphinegold groups: X-ray crystal structures of [AuRu3(µ-H)2(µ-COMe)(CO)9(PPh3)], [Au3Ru3(µ-COMe)(CO)9(PPh3)3], and [Au3Ru4(µ-H)(CO)12(PPh3)3]

L. Bateman, Michael Green, Judith A. K. Howard, Kevin A. Mead, Rona M. Mills, Ian D. Salter, F. G. A. Stone, Peter Woodward

Journal of the Chemical Society Chemical Communications · 1982 · 28 citations · 0 references

DOI

Concepts

Natural SciencesChemistryMaterials ScienceCrystal StructureInorganic ChemistryOrganometallic ChemistryCoordination ChemistryCrystal ChemistryCrystallographyMetal-ligand BondingTransition Metal ComplexesX-ray CrystallographyCoordination Geometry DeterminationElectronic Structure Of Metal ComplexesLanthanide Coordination ChemistryLanthanide HydridesMetal HydridesX-ray Diffraction Analysis

Abstract

The compounds [Ru3(µ-H)3-COMe)(CO)9 and [Ru4(µ-H)4(CO)12] react with [AuMe(PPh3)] to give gold–ruthenium cluster compounds, and the structures of [AuRu3(µ-H)2(µ3-COMe)(CO)9(PPh3)], [Au3Ru3(µ3-COMe)(CO)9(PPh3)3], and [Au3Ru4(µ-H)(CO)12(PPh3)3] have been established by single-cryst X-ray diffraction studies.