An Isoreticular Series of Metal–Organic Frameworks with Dendritic Hexacarboxylate Ligands and Exceptionally High Gas‐Uptake Capacity

Abstract

Holding gas: One of the isoreticular metal–organic frameworks (MOFs) that have been synthesized and characterized structurally, PCN-68 (see structure), has a Langmuir surface area of as high as 6033 m2 g−1. The MOFs also display excellent gas (H2, CH4, and CO2) adsorption capacity.