Recueil des Travaux Chimiques des Pays-Bas · 1960 · 71 citations · 1 references
Natural SciencesElectrical EngineeringMaterials ScienceAnalytical ChemistryElectrochemical EngineeringElectrochemistryElectrochemical CellsElectrode KineticsElectrode MaterialsElectrode-electrolyte InterfacesElectrolytic CellsGalvanic CellsDouble Layer TheoryElectrochemical CharacterizationElectrochemical Impedance AnalysisImpedance TheoryInterfacial Impedance
Abstract It is shown by experiment that both types of frequency dependency of the cell impedance, treated in Part I, occur. From the results the diffusion constant of the Hg ++ 2 ion in 1 M HClO 4 and the reaction rate constant of the zinc amalgam electrode in 1 M NaClO 4 + 10 −3 M HClO 4 base electrolyte are calculated. In addition the value of the double layer capacity of the zinc amalgam electrode is reported.
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