Concepedia

Spin crossover intermediate plateau stabilization in a flexible 2-D Hofmann-type coordination polymer

Y. Maximilian Klein, Natasha F. Sciortino, Florence Ragon, Catherine E. Housecroft, Cameron J. Kepert, Suzanne M. Neville

Chemical Communications · 2014 · 88 citations · 29 references

DOI

Concepts

Abstract

The abrupt and hysteretic two-step spin crossover in a new triazole-based 2-D Hofmann-type complex shows a record breaking 120 K intermediate plateau (IP) region stabilized by negative cooperative interactions.

References

29

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Spin state switching in iron coordination compounds

Philipp Gütlich, A.B. Gaspar, Yann Garcia · Beilstein Journal of Organic Chemistry · 2013 · 724 citations · Full text

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Cooperative Spin Crossover Behavior in Cyanide-Bridged Fe(II)−M(II) Bimetallic 3D Hofmann-like Networks (M = Ni, Pd, and Pt)

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