Self‐Assembly of Semifluorinated Janus‐Dendritic Benzamides into Bilayered Pyramidal Columns

Abstract

Two faces: Semifluorinated Janus-dendritic benzamides self-assemble into supramolecular bilayered pyramidal columns with diameters over twofold greater than those of columns generated from twin-dendritic benzamides (see model). The Janus-dendritic benzamides are synthesized by selectively replacing the aliphatic chains from the periphery of one of the two dendrons of a twin-dendritic benzamide with semifluorinated chains. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2005/z501254_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.