Nitroxyl Radical Self‐Assembled Monolayers on Gold: Versatile Electroactive Centers in Aqueous and Organic Media

Abstract

Nitroxyl radical SAMs on gold afford a noteworthy electrochemical stability in both aqueous and organic media (see figure). The control of the redox center accessibility using mixed SAMs is illustrated by the electrocatalytic activities towards benzyl-alcohol oxidation in CH2Cl2 and H2O. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.