Redox‐Controlled Magnetic {Mn₁₃} Keggin Systems

Abstract

Stronger magnetic moment with fewer electrons: An α-Keggin-type {Mn13} single-molecule magnet (SMM) was synthesized and subsequently oxidized (see picture); its one- and two-electron-oxidized derivatives could be isolated. The spin ground states of the more oxidized species are higher despite the electron loss, resulting in amplification of the SMM properties. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.