A High‐Conductivity Crystal Containing a Copper(I) Coordination Polymer Bridged by the Organic Acceptor TANC

Abstract

Molecular conductors: A new, modifiable electron acceptor with a 5,6,11,12-tetraazanaphthacene (TANC) framework was introduced in CuI–TANC coordination polymers (see picture). The conduction mechanism of a high-conductivity crystal constructed from these polymers can be described as 1D variable-range hopping based on the disordered F− ions. Supporting information for this article is available on the WWW under http://www.wiley-vch.de/contents/jc_2002/2006/z600553_s.pdf or from the author. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.