Angewandte Chemie International Edition in English · 1978 · 13 citations · 2 references
Natural SciencesChemistryOrganic ChemistryOrganic SynthesisAmide Bond Formation
N-Aryl-β-mercaptothioamides (2) are formed by an unexpected reaction of the unsaturated amides (1) with P4S10/NaHCO3. Under these conditions carbonyl compounds are known to undergo transformation into thiocarbonyl compounds
2