Concepedia

Ruthenium-catalysed conversion of triynes to benzene derivatives—a novel metathesis cascade

Jens‐Uwe Peters

Chemical Communications · 1997 · 64 citations · 14 references

DOI

Concepts

Abstract

In a novel application of [PhCH [[double bond, length half m-dash]] Ru(PCy)Cl] 1, triynes are isomerised to benzene derivatives; a cascade of four metathesis reactions is proposed as a mechanistic explanation.

References

14

Synthesis and Applications of RuCl<sub>2</sub>(CHR‘)(PR<sub>3</sub>)<sub>2</sub>:  The Influence of the Alkylidene Moiety on Metathesis Activity

Peter Schwab, Robert H. Grubbs, Joseph W. Ziller · Journal of the American Chemical Society · 1996 · 2.1K citations

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Application of Ring-Closing Metathesis to the Synthesis of Rigidified Amino Acids and Peptides

Scott J. Miller, Helen E. Blackwell, Robert H. Grubbs · Journal of the American Chemical Society · 1996 · 431 citations

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Transition-metal-catalyzed acetylene cyclizations in organic synthesis

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Catalytic Ring Closing Metathesis of Dienynes:  Construction of Fused Bicyclic [<b><i>n</i></b>.<b><i>m.0] Rings</i></b>

Soong‐Hoon Kim, William J. Zuercher, Ned B. Bowden et al. · The Journal of Organic Chemistry · 1996 · 230 citations

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Supramolecular Design by Covalent Capture. Design of a Peptide Cylinder via Hydrogen-Bond- Promoted Intermolecular Olefin Metathesis

Thomas D. Clark, M. Reza Ghadiri · Journal of the American Chemical Society · 1995 · 184 citations

, , +12