Superoxide-stable ionic liquids: new and efficient media for electrosynthesis of functional siloxanes

Abstract

The electrogeneration of diorganylsilanones from difunctional precursors Y(CH(2))(3)(Me)SiX(2) and Ph(2)SiX(2)(Y = NH(2), CF(3), CN; X = Cl, OEt, OMe), performed in the presence of hexamethyldisiloxane or hexamethylcyclotrisiloxane (D(3)) in the ionic liquids [C(5)H(5)NC(8)F(18)].NTf(2), [C(5)H(5)NC(18)H(38)].NTf(2) and Me(3)BuN.NTf(2), which reveal high solubility of oxygen and are inert toward superoxide anion, allows functionalized siloxanes to be produced selectively in good isolated yields.