δ ¹³ C and δ ² H measurement of methane from ecological and geological sources by gas chromatography/combustion/pyrolysis isotope‐ratio mass spectrometry

Abstract

The automated measurement of δ(13)C-CH4 and δ(2)H-CH4 values, from ambient to percentage concentrations, is possible with minimal modifications to a commercial preconcentration/gas chromatography inlet. Sample matrix interferences (CO2 , Cn Hy , air) are eliminated and simultaneous isotopic measurements of methane and CO2 and/or C1 -C4 light hydrocarbons are possible, while still retaining functionality for isotopic measurements of other gas species (e.g. CO2, N2, O2).