Concepedia

Publication | Closed Access

[Mn<sup>III</sup>(salen)]<sub>6</sub>[Fe<sup>III</sup>(bpmb)(CN)<sub>2</sub>]<sub>6</sub>⋅7 H<sub>2</sub>O: A Cyanide‐Bridged Nanosized Molecular Wheel

165

Citations

49

References

2005

Year

Abstract

Heterometallic wheel: A cyanide-bridged heterometallic dodecanuclear complex featuring a nanosized molecular wheel has been synthesized based on magnetically anisotropic [Mn(salen)]+ and [Fe(bpmb)(CN)2]− building blocks. Magnetic studies reveal that the complex exhibits overall ferromagnetic intramolecular coupling (see picture) and frequency-dependent ac magnetic susceptibility. H2bpmb=1,2-bis(pyridine-2-carboxamido)-4-methylbenzene.

References

YearCitations

Page 1