Publication | Closed Access
Convergent total synthesis of lamellarin K†
86
Citations
8
References
1997
Year
Azomethine YlideEngineeringHeterocyclicBiochemistryPyrrole 25Organic ChemistryDihydroisoquinolinium Salt 24Heterocycle ChemistryPharmacologyPharmaceutical ChemistrySynthetic ChemistryBiomolecular EngineeringConvergent Total SynthesisNatural Product Synthesis
The azomethine ylide derived from dihydroisoquinolinium salt 24 undergoes an intramolecular [3 + 2] cycloaddition reaction to give pyrrole 25 which upon de-isopropylation affords the marine alkaloid lamellarin K 4.
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