Concepedia

Terminal ruthenium carbido complexes as σ-donor ligands

Andrew Hejl, Tina M. Trnka, Michael W. Day, Robert H. Grubbs

Chemical Communications · 2002 · 101 citations · 17 references

DOI

Concepts

Abstract

The terminal carbido ligand of (PCy3)2(Cl)2RuC coordinates to other metal centers in a σ-donor fashion, as in (PCy3)2(Cl)2RuC–Pd(Cl)2(SMe2) and (PCy3)2(Cl)2RuC–Mo(CO)5.

References

17

The Development of L<sub>2</sub>X<sub>2</sub>RuCHR Olefin Metathesis Catalysts:  An Organometallic Success Story

Tina M. Trnka, Robert H. Grubbs · Accounts of Chemical Research · 2000 · 3.5K citations

, , +16

Reactions of Ruthenium Carbenes of the Type (PPh3)2(X)2Ru:CH-CH:CPh2 (X = Cl and CF3COO) with Strained Acyclic Olefins and Functionalized Olefins

Zhe Wu, SonBinh T. Nguyen, Robert H. Grubbs et al. · Journal of the American Chemical Society · 1995 · 216 citations

, , +5

A terminal molybdenum carbide prepared by methylidyne deprotonation

Jonas C. Peters, Aaron L. Odom, Christopher C. Cummins · Chemical Communications · 1997 · 155 citations · Full text

, , +11

Atomic Carbon as a Terminal Ligand:  Studies of a Carbidomolybdenum Anion Featuring Solid-State <sup>13</sup>C NMR Data and Proton-Transfer Self-Exchange Kinetics

Jane B. Greco, Jonas C. Peters, Thomas A. Baker et al. · Journal of the American Chemical Society · 2001 · 138 citations

, , +15

The Metathesis-Facilitated Synthesis of Terminal Ruthenium Carbide Complexes:  A Unique Carbon Atom Transfer Reaction

Robert G. Carlson, Melanie A. Gile, Joseph A. Heppert et al. · Journal of the American Chemical Society · 2002 · 115 citations

, , +8