Publication | Closed Access
Speciation and decomposition pathways of ruthenium catalysts used for selective C–H hydroxylation
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Citations
43
References
2014
Year
EngineeringMechanistic InsightMetal ComplexChemistryChemical EngineeringAnalytical ChemistryOrganometallic CatalysisRedox ChemistryHomogeneous CatalysisInorganic ChemistryBiochemistryRuthenium CatalystsCatalysisDecomposition PathwaysCatalytic SynthesisC–h Hydroxylation ReactionNatural SciencesMass SpectrometryHeterogeneous CatalysisSelective C–h HydroxylationMolecular Catalysis
Mechanistic insight into the C–H hydroxylation reaction catalysed by [(Me<sub>3</sub>tacn)RuCl<sub>3</sub>] has been obtained using desorption electrospray ionization mass spectrometry (DESI-MS) to identify reactive intermediates and to determine the fate of the starting metal complex.
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