Mechanically controllable break-junctions for use as electrodes for molecular electronics

Abstract

We discuss the use of mechanically controllable break-junctions (MCBs) as electrodes for contacting individual objects such as clusters or molecules. A big advantage of MCB electrodes is the possibility of varying the contact geometry and, accordingly, the contact resistances and the quantum coherent transport properties between the object under study and the electrodes. We compare the suitability of single-atom contacts of different elements as electrode material. Finally, we present preliminary results on electronic transport through individual (or a few) fullerene molecules contacted by gold MCB electrodes. The typical resistances are in the order of the quantum of conductance. The circuits sustain voltages of the order of 1 V and are mechanically more stable than single-atom contacts between the gold electrodes alone.