Angewandte Chemie International Edition · 2002 · 145 citations · 29 references
Natural SciencesChemistryOrganic ChemistryOrganometallic ChemistryPolymer ChemistryCoordination ChemistryCoordination PolymersMetal-ligand BondingPolymer NetworksPolymer StructureTransition Metal ComplexesCoordination Polymer SynthesisCoordination PolymerizationLinkingMetal-ligand Coordination PolymersMetallocene SynthesisOne-dimensional Coordination PolymersTwo-dimensional Coordination Polymers
Different copper halide, different copper product: The cyclo-P5-ligand complex [Cp*Fe(η5-P5)] (1; Cp*=C5Me5) reacts with CuBr and CuI to give two-dimensional networks in which 1 is the linking unit. However, a novel one-dimensional-chain coordination polymer (see picture) is formed with CuCl.
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Frameworks for Extended Solids: Geometrical Design Principles
M. O’Keeffe, Mohamed Eddaoudi, Hailian Li et al. · Journal of Solid State Chemistry · 2000 · 897 citations