Polar and Magnetic Mn₂FeMO₆ (M=Nb, Ta) with LiNbO₃‐type Structure: High‐Pressure Synthesis

Abstract

Polar LiNbO3-type magnetic oxides have been extended, for the first time, to the A2BB′O6 family. Mn2+2Fe3+M5+O6 (M=Nb, Ta), synthesized at high pressure, adopt a polar structure, as demonstrated by electron diffraction and the second harmonic generation effect, and they have interesting magnetic properties. As a service to our authors and readers, this journal provides supporting information supplied by the authors. Such materials are peer reviewed and may be re-organized for online delivery, but are not copy-edited or typeset. Technical support issues arising from supporting information (other than missing files) should be addressed to the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article.