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A novel mass-spectroscopic technique for the investigation of vapour-phase tautomeric equilibria
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1979
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EngineeringExperimental ThermodynamicsComputational ChemistryChemistryIon ProcessChemical Ionisation ProtonationSpectra-structure CorrelationAnalytical ChemistryThermodynamicsEquilibrium Thermodynamic PropertyBiophysicsCollision-induced Dissociation–massNovel Mass-spectroscopic TechniquePhysicsPhysical ChemistryQuantum ChemistryIon MobilityPhase EquilibriumNatural SciencesMass SpectrometryChemical KineticsVapour-phase Tautomeric EquilibriaIon Kinetic EnergyIon Structure
Comparison of collision-induced dissociation–mass analysed ion kinetic energy (CID–MIKE) spectra of cations found by chemical ionisation ethylation with those of chemical ionisation protonation of fixed ethyl derivatives, allows identification of predominant tautomers in vapour phase equilibria.