Catalytic Conversion of Aldehydes into Higher α‐Siloxy Aldehydes by Hydrosilane and Carbon Monoxide

Shinji Murai, Toshikazu Kato, Noboru Sonoda, Yoshio Seki, Kazuaki Kawamoto

Angewandte Chemie International Edition in English · 1979 · 30 citations · 5 references

Concepts

Abstract

Chain lengthening and functionalization of aldehydes–leaving the aldehyde group intact–are possible with the aid of the reaction shown below. The products (2) are useful intermediates which are otherwise difficult to prepare.

References

5