Concepedia

Reactivity of unsaturated clusters. Phosphoruscarbon bond activation, hydrogen migration and acetylene interconversion in the reactions of 46-electron (H)Ru3(CO)9(μ-PPh2) with Ph2PCCR (R = Ph, But, Pri). X-ray structure of Ru3(CO)9(μ-PPh2)2(μ3-η2-HCCPh): a new type of 5-vertex, 7-skeletal pair cluster

Françoise Van Gastel, Shane Maclaughlin, M. W. LYNCH, Arthur J. Carty, Enrico Sappa, António Tiripicchio, Marisa Tiripicchio Camellini

Journal of Organometallic Chemistry · 1987 · 24 citations · 26 references

DOI

Concepts

References

26

Structural chemistry and reactivity of cluster bound acetylides: close relatives of the carbides?

Arthur J. Carty · Pure and Applied Chemistry · 1982 · 195 citations · Full text

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Multiple metal-carbon bonds. 38. Preparation of trialkoxymolybdenum(VI) alkylidyne complexes, their reactions with acetylenes, and the x-ray structure of Mo[C3(CMe3)2][OCH(CF3)2](C5H5N)2

Laughlin G. McCullough, Richard R. Schrock, John C. Dewan et al. · Journal of the American Chemical Society · 1985 · 180 citations

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Selective metal-ligand interactions in hetero-metallic transition metal clusters

Enrico Sappa, António Tiripicchio, Pierre Braunstein · Coordination Chemistry Reviews · 1985 · 166 citations

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Synthesis and characterization of the fluxional species H2Os3(CO)10L. Crystal structure of dihydroundecacarbonyltriosmium

John R. Shapley, Jerome B. Keister, Melvyn Rowen Churchill et al. · Journal of the American Chemical Society · 1975 · 90 citations

, , +9

The synthesis of [Ru<sub>5</sub>C(CO)<sub>15</sub>] by the carbonylation of [Ru<sub>6</sub>C(CO)<sub>17</sub>] and the reactions of the pentanuclear cluster with a variety of small molecules: the X-ray structure analyses of [Ru<sub>5</sub>C(CO)<sub>15</sub>], [Ru<sub>5</sub>C(CO)<sub>15</sub>(MeCN)], [Ru<sub>5</sub>C(CO)<sub>14</sub>(PPh<sub>3</sub>)], [Ru<sub>5</sub>C(CO)<sub>13</sub>(PPh<sub>3</sub>)<sub>2</sub>], and [Ru<sub>5</sub>(µ-H)<sub>2</sub>C(CO)<sub>12</sub>{Ph<sub>2</sub>P(CH<sub>2</sub>)<sub>2</sub>PPh<sub>2</sub>}]

Brian F. G. Johnson, Jack Lewis, J. Nicola Nicholls et al. · Journal of the Chemical Society Dalton Transactions · 1983 · 88 citations

, , +11