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Methanolic trimethylamine mediated Baylis-Hillman reaction
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2002
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Chemical EngineeringMinimum NumberEngineeringCross-coupling ReactionMethanolOrganic ChemistryCatalysisTertiary AmineChemistryMethanolic TrimethylamineSynthetic ChemistryBiomolecular Engineering
Application of methanolic trimethylamine, the tertiary amine containing minimum number of carbon atoms with lowest possible molecular weight, for mediating the Baylis−Hillman coupling of various aldehydes with activated olefins viz. methyl acrylate, acrylonitrile and acrolein is described.