Concepedia

New Products from PCl<sub>3</sub>, P(NMe<sub>2</sub>)<sub>3</sub>, and AlCl<sub>3</sub>

Alfred Schmidpeter, Siegfried Lochschmidt

Angewandte Chemie International Edition in English · 1986 · 38 citations · 6 references

DOI

Concepts

Abstract

Exploitation of an old and frequently studied reaction (to obtain new compounds) has proven successful with the system PCl3/P(NMe2)3/AlCl3. Depending on the sequence in which the reaction partners are allowed to react with each other, different products are formed. The most interesting new products are the diphosphoniodiphosphirane ion 1 (the CH2 group comes from the solvent CH2Cl2) and the cyclotetraphosphane ion 2.

References

6

Symmetrical and Unsymmetrical Triphosphenium Ions

Alfred Schmidpeter, Siegfried Lochschmidt, William S. Sheldrick · Angewandte Chemie International Edition in English · 1985 · 89 citations

, , +9

Structure of [2((CH3)2N)2PCl].AlCl3, ((CH3)2N)3P.((CH3)2N)2PCl.AlCl3, and related species-diphosphorus cations

C. W. Schultz, R. W. Parry · Inorganic Chemistry · 1976 · 69 citations

, , +7

2‐Phosphaallyl Cations by Formal Insertion of P<sup>⊕</sup> into the CC Double Bond

Alfred Schmidpeter, Siegfried Lochschmidt, Angela Willhalm · Angewandte Chemie International Edition in English · 1983 · 60 citations

, , +6

Beiträge zur Chemie des Phosphors, 85 Synthese und Eigenschaften der Diphosphirane (t-BuP)<sub>2</sub>CMe<sub>2</sub> und (t-BuP)<sub>2</sub>CH<sub>2</sub> Contributions to the Chemistry of Phosphorus, 85 Synthesis and Properties of the Diphosphiranes (t-BuP)<sub>2</sub>CMe<sub>2</sub> and (t-BuP)<sub>2</sub>CH<sub>2</sub>

Marianne Bäudler, F. Saykowski · Zeitschrift für Naturforschung B · 1978 · 50 citations · Full text

, , +6

Exchange of Parts between Molecules at Equilibrium. III. Nonrandom Redistribution of Dialkylamino Groups and halogens on Triply Connected Phosphorus

John R. VanWazer, Ludwig Maier · Journal of the American Chemical Society · 1964 · 46 citations

, , +5