Publication | Open Access
Dynamical First-Order Phase Transition in Kinetically Constrained Models of Glasses
412
Citations
28
References
2007
Year
EngineeringEast ModelPhysicsGlass TransitionNatural SciencesGlass-forming LiquidApplied PhysicsNumerical SimulationGlass MaterialGlass FormersContinuum ModelingKinetically Constrained ModelsTransformation KineticsComputational MechanicsDynamic Facilitated ModelsMathematical Statistical PhysicMultiscale Modeling
We show that the dynamics of kinetically constrained models of glass formers takes place at a first-order coexistence line between active and inactive dynamical phases. We prove this by computing the large-deviation functions of suitable space-time observables, such as the number of configuration changes in a trajectory. We present analytic results for dynamic facilitated models in a mean-field approximation, and numerical results for the Fredrickson-Andersen model, the East model, and constrained lattice gases, in various dimensions. This dynamical first-order transition is generic in kinetically constrained models, and we expect it to be present in systems with fully jammed states.
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