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Synthesis of Enantiopure 1‐<i>r</i>‐Aryl‐2‐<i>c</i>,5‐<i>t</i>‐diphenylphospholane Oxides and Boranes by Pd‐Catalyzed C–P Bond Formation
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2005
Year
Chemical EngineeringEnantioselective SynthesisEngineeringCross-coupling ReactionChiral PhosphaneOrganic ChemistryCatalysisChemistryEnantiopure 1‐Asymmetric CatalysisBoranes 5Synthetic ChemistryVarious Aryl Derivatives
Abstract New chiral enantiopure phospholane oxides 1 and boranes 5 were obtained from efficient carbon–phosphorus bond formation by organocuprate or palladium‐catalyzed reactions. C–P cross‐coupling reactions between chiral phosphane oxide 3 or borane 4 and various aryl derivatives are presented.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)
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