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Room-temperature spin crossover and Langmuir–Blodgett film formation of an iron(ii) triazole complex featuring a long alkyl chain substituent: the tail that wags the dog

Jonathan A. Kitchen, Nicholas G. White, Claudio Gandolfi, Martin Albrecht, Guy N. L. Jameson, J. L. Tallon, Sally Brooker

Chemical Communications · 2010 · 70 citations · 20 references

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Abstract

[Fe(II)(C(16)dpt)(2)(NCS)(2)].(2/3)H(2)O displays temperature-mediated spin crossover (SCO) with T((1/2)) = 290 K and the long alkyl chain substituent on the dipyridyltriazole ligand facilitates the formation of a stable Langmuir-Blodgett film at an air-water interface.

References

20

Spin crossover in iron(II) complexes of 3,5-di(2-pyridyl)-1,2,4-triazoles and 3,5-di(2-pyridyl)-1,2,4-triazolates

Jonathan A. Kitchen, Sally Brooker · Coordination Chemistry Reviews · 2007 · 187 citations

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Spin-crossover in the [Fe(abpt)2(NCX)2] (X=S, Se) system: structural, magnetic, calorimetric and photomagnetic studies

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Supramolecular Assembly at Interfaces:  Formation of an Extended Two-Dimensional Coordinate Covalent Square Grid Network at the Air−Water Interface

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From <i>N</i>‐Substituted Thioamides to Symmetrical and Unsymmetrical 3,4,5‐Trisubstituted 4<i>H</i>‐1,2,4‐Triazoles: Synthesis and Characterisation of New Chelating Ligands

M.H. Klingele, Sally Brooker · European Journal of Organic Chemistry · 2004 · 115 citations

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