Publication | Open Access
Second-generation fluorous chiral (salen) manganese complexes
55
Citations
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References
2000
Year
Inorganic ChemistryChemical EngineeringEngineeringCoordination ComplexManganese ComplexesFluorous Biphasic ConditionsOrganic ChemistryOrganometallic CatalysisCatalysisSecond-generation Fluorous ChiralChemistryMolecular ComplexLong Perfluoroalkyl SubstituentsAsymmetric CatalysisEnantioselective Synthesis
Sterically hindered chiral (salen)manganese complexes bearing long perfluoroalkyl substituents are synthesized and successfully employed as catalysts in the enantioselective (ee = 50–87%) epoxidation of alkenes under fluorous biphasic conditions.
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