Enantioselective Deprotonation of Alkyl Carbamates by Means of (R,R)-1,2-Bis(N,N-dimethylamino)cyclohexane/sec-Butyllithium— Theory and Experiment

E.‐U. Würthwein, Karin Behrens, Dieter Hoppe

Chemistry - A European Journal · 1999 · 40 citations · 0 references

Concepts

Abstract

The energies of the diastereomorphic transition states lk-F and ul-F (see scheme) of the deprotonation reaction were calculated and compared with the experimentally observed results.