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Photoelectrochemical CO<sub>2</sub> reduction using a Ru(<scp>ii</scp>)–Re(<scp>i</scp>) multinuclear metal complex on a p-type semiconducting NiO electrode
135
Citations
12
References
2015
Year
EngineeringHybrid ElectrodeInorganic PhotochemistrySynthetic PhotochemistryMetal ComplexPhoto-electrochemical CellNio ElectrodeChemistryPhotoelectrochemistrySelective PhotoexcitationChemical EngineeringPhotocatalysisElectrode Reaction MechanismMaterials ScienceInorganic ChemistryPhotochemistrySurface ElectrochemistryCatalysisElectrochemistryOxygen Reduction Reaction
A photocathode for CO2 reduction was successfully developed using a hybrid electrode comprising a Ru(II)-Re(I) supramolecular photocatalyst and a NiO electrode. Selective photoexcitation of the Ru photosensitizer unit of the photocatalyst at -1.2 V vs. Ag/AgNO3 selectively afforded CO with high faradaic efficiency.
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