An oxime–carbapalladacycle complex covalently anchored to silica as an active and reusable heterogeneous catalyst for Suzuki cross-coupling in water

Abstract

A preformed oxime-carbapalladacycle complex covalently anchored onto mercaptopropyl modified silica is highly active (> 99%) for the Suzuki reaction of p-chloroacetophenone and phenylboronic acid in water; no leaching occurs and the same catalyst sample was reused eight times without decreased activity.