Concepedia

Binding of Molecular Magnesium Hydrides to a Zirconocene–Enyne Template

Georg Bender, Thomas Wiegand, Hellmut Eckert, Roland Fröhlich, Constantin G. Daniliuc, Christian Mück‐Lichtenfeld, Sylvester Ndambuki, Tom Ziegler, Gerald Kehr, Gerhard Erker

Angewandte Chemie International Edition · 2012 · 26 citations · 43 references

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Abstract

An enyne–zirconium complex stabilizes molecular magnesium hydride (MgH2) and even a molecular hydride, nC4H9MgH. These systems feature magnesium olefin π complexation.

References

43

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Stefan Grimme, Jens Antony, Stephan Ehrlich et al. · The Journal of Chemical Physics · 2010 · 56.9K citations

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Dirk Andrae, Michael Dolg, Hermann Stoll · Theoretica Chimica Acta · 1990 · 8.5K citations

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